Synthesis of Crystalline, Mesoporous Metal Oxide Catalysts for Environmental and Energy Applications
Digital Document
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http://hdl.handle.net/11134/20002:860651074
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Persons |
Persons
Creator (cre): Luo, Zhu
Major Advisor (mja): Suib, Steven L.
Associate Advisor (asa): Alpay, S. Pamir
Associate Advisor (asa): Nieh, Mu-Ping
Associate Advisor (asa): Angeles-Boza, Alfredo
Associate Advisor (asa): Hay, Stephen O.
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Title |
Title
Title
Synthesis of Crystalline, Mesoporous Metal Oxide Catalysts for Environmental and Energy Applications
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Origin Information
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Parent Item
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Digital Origin |
Digital Origin
born digital
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Description |
Description
The main goal of this dissertation study is to develop high activity heterogeneous catalysts (metal oxide materials) for environmental and sustainable energy applications. Controlled synthesis of crystalline structures, physical,and chemical properties of the catalysts result in improved catalytic activity. Four different topics including photocatalytic remediation, hydrogen evolution, electrochemical supercapacitors, and organic synthesis applications are discussed in this thesis. The first part presents a unique inverse micelle preparation method to synthesize mesoporous mixed phase (anatase/rutile) titanium dioxide materials. This study was conducted with the purpose of developing an inexpensive, environmentally friendly, and visible light active photocatalyst. The prepared vanadium doped mesoporous TiO2 materials show enhanced photocatalytic activity for decomposing organic pollutants compared to commercial TiO2 (Degussa P25). The second part exhibits the preparation of copper modified titanium dioxides materials for terminal alkyne homocoupling reactions. The mesoporous TiO2 was used as a support. The focus of this study is to investigate how the different preparation methods (doping, solvent free, and impregnation) and the various forms of copper affect the homocoupling yields. The Cu doped TiO2 material shows the best homocoupling activity with high yield more than 99%. In the third part of this thesis, mesoporous MoO3-x materials was prepared via a novel method. The prepared MoO3-x material has a crystalline, mesoporous, and oxygen-deficient structure. The unique physical and chemical properties of MoO3-x make it a potential replacement for Pt materials in hydrogen evolution reactions. The MoO3-x material can be used in both alkaline and acidic media without the assistance of any noble metal catalysts. Further optimization of this study may lead to the low-cost metal oxide catalysts in practical electrochemical applications.
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Genre
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Organizations
Degree granting institution (dgg): University of Connecticut
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Rights Statement
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Use and Reproduction |
Use and Reproduction
These materials are provided for educational and research purposes only.
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Local Identifier |
Local Identifier
OC_d_1040
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